Calcium fluoride , CaF2 , Isometric cubic habit
Color | Colorless, although samples are often deeply colored owing to impurities; Purple, lilac, golden-yellow, green, blue, pink, champagne, brown. |
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Crystal habit | Well-formed coarse sized crystals; also nodular, botryoidal, rarely columnar or fibrous; granular, massive |
Twinning | Common on {111}, interpenetrant, flattened |
Cleavage | Octahedral, perfect on {111}, parting on {011} |
Fracture | Subconchoidal to uneven |
Mohs scale hardness | 4 (defining mineral) |
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Luster | Vitreous |
Streak | White |
Specific gravity | 3.175–3.184; to 3.56 if high in rare-earth elements |
Optical properties | Isotropic; weak anomalous anisotropism |
Fluorite has four perfect cleavage planes that help produce octahedral fragments.
Element substitution for the calcium cation often includes strontium and certain rare earth elements (REE), such as yttrium and cerium.
Fluorite forms as a late-crystallizing mineral in felsic igneous rocks typically through hydrothermal activity. It is particularly common in granitic pegmatites. It may occur as a vein deposit formed through hydrothermal activity particularly in limestones. In such vein deposits it can be associated with galena, sphalerite, barite, quartz, and calcite. Fluorite can also be found as a constituent of sedimentary rocks either as grains or as the cementing material in sandstone.
Pure fluorite is transparent, both in visible and ultraviolet light, but impurities usually make it a colorful mineral. The fluorescence of fluorite may be due to mineral impurities, such as yttrium and ytterbium, or organic matter, such as volatile hydrocarbons in the crystal lattice. Fluorescence involves the elevation of electron energy levels by quanta of ultraviolet light, followed by the progressive falling back of the electrons into their previous energy state, releasing quanta of visible light in the process. In fluorite, the visible light emitted is most commonly blue, but red, purple, yellow, green, and white also occur.
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